a. Conceptual image of the large-scale polymer metasurface cooling film cool down the earth under sunlight. b. A photo of the large-scale and flexible polymer metasurface cooling film. c. An SEM image of the microstructures in the polymer metasurface cool
a. Conceptual image of the large-scale polymer metasurface cooling film cool down the earth under sunlight. b. A photo of the large-scale and flexible polymer metasurface cooling film. c. An SEM image of the microstructures in the polymer metasurface cool
CHINA, October 25, 2023 /EINPresswire.com/ -- An ideal radiative cooler requires accurate spectral control capability with high efficiency, stability, and scalability. Flexible cooling films represent a cost-effective solution but lack of accuracy in spectral control. Polymer metasurface with periodically arranged three-dimensional (3D) trench structures made by roll-to-roll printing can provide high-performance radiative cooling. The impressive cooling power and temperature deduction on a clear sky midday have been achieved, promising broad practical applications in energy saving and passive heat dispersion fields.
Domestic and industrial thermal management accounts for a significant portion of global energy consumption. Effectively maintaining the desired temperature with minimum energy input is critical from both economic and environmental points of view. Indoor thermal management is usually achieved by air conditioning (AC). This consumes a huge amount of energy. By 2023, the world's annual AC energy consumption is expected to exceed hundreds of billions of dollars. This sum will be worsened by the continuous cooling requirements (24/7) from an increasing number of large data centers. Severe economic burden and deteriorated environment have placed an urgent need for renewable cooling techniques with minimum energy input.
In a new paper published in eLight, a team of scientists, led by Professor Baohua Jia of RMIT University in Melbourne, have developed a roll-to-roll polymer film for improved radiative cooling. The novel technique is a metasurface concept enabled by arranging 3D trench-like structures within the thin layer of the polymer film.
Conventional heat dissipation usually requires extra energy consumption. Radiative cooling technology has attracted widespread attention due to its unique capability of emitting thermal radiation into outer space. This cools the object consuming no energy. An ideal radiative cooler should have high emissivity within the earth’s atmospheric transparency window. The radiative coolers should strongly reflect solar irradiation to prevent being heated up by sunlight. Therefore, the ability to flexibly and accurately manipulate spectra in a large range holds the key to achieving high cooling performance but remains challenging.
Radiative cooling effects have been successfully demonstrated in three distinct types. The types are based on materials used and structural engineering strategies: polymers, multilayer thin films, and metamaterials. Among these designs, polymer films have shown many attractive features. They include low solar absorption, relatively high emissivity in the atmospheric transparency windows, low cost, and scalability, which make them very promising for real-life applications.
However, only based on the intrinsic material absorption properties without nanostructural engineering, their ability to achieve unity IR emissivity and solar reflectance at desired broad bandwidth is significantly limited. Although embedding randomly distributed particles can improve spectral controllability, achieving a precisely controlled spectrum is challenging.
Metamaterials based on periodic structures have demonstrated outstanding spectral manipulation capability for diurnal radiative cooling. But metamaterial radiative coolers are based on rigid substrates with large thicknesses, which cannot be integrated with objects with arbitrary shapes. More importantly, due to the fabrication challenges of the periodic micro/nanostructures, they are limited to small areas and, therefore, not suitable for real-life applications.
The research team enabled precise spectrum manipulation capability in thin polymer materials by designing periodic trench-like metasurface structures. They then fabricated them using the manufacturing-friendly roll-to-roll printing technique. The 50-μm-thick polymer metasurface radiative cooling (PMRC) film reflects almost all the incident sunlight. At the same time, it strongly emits thermal radiation in the atmospheric transparency windows. This results in an outstanding cooling performance all day.
The film can be integrated easily into various devices, such as a water tank, a COVID protective suit, and a car cover, achieving excellent cooling performance. The large-scale roll-to-roll fabricated flexible PMRC film is cost-effective and readily attachable to any object for broad cooling applications, meeting stringent cooling needs without energy consumption. The PMRC film presents omnidirectional absorption and emission while offering superior cooling performance. It also provides flexibility, scalability, and good stability, promising enormous practical applications in thermal management.
Funding:
This work was supported by the Australia Research Council through the Discovery Project scheme (Grant No. DP190103186, DP220100603), the Industrial Transformation Training Centres scheme (Grant No. IC180100005), the Future Fellowship scheme (Grant No. FT210100806, No. FT220100559), the Discovery Early Career Researcher Award scheme (Grant No. DE230100383), the Suzhou Science and Technology Plan (Grant No. SYG202118) and the Natural Science Foundation of Shandong Province (Grant No. ZR2021ME162).
DOI: 10.1186/s43593-023-00053-3
Original URL: https://doi.org/10.1186/s43593-023-00053-3
Lucy Wang
BioDesign Research
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